
TY  - JOUR
A1  - Healy, PC 
A1  - Kildea, JD 
A1  - Skelton, BW 
A1  - White, AH 
T1  - Lewis-Base Adducts of Group 11 Metal(I) Compounds. XLI. Conformational Systematics of [(N-base)<sub>1</sub>(CuX)<sub>1</sub>]<sub>&#8734;</sub> 'Skewed Stair' Polymers [N-base = (Substituted) Pyridine]
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1989
VL  - 42
IS  - 1
SP  - 93
EP  - 105
KW  - 
UR  - https://doi.org/10.1071/CH9890093 
N2  - In contrast to the symmetrical 'orthogonal' 'stair' polymers recorded in the previous paper, a variety of distorted ('skewed') stair polymer systems have been synthesized and structurally characterized by using substituted pyridine bases. The structure of CuBr/pyridine (1 : 1) is recorded, completing the series for pyridine with all halides (CI, Br, I), together with full halide arrays for the bases pyridine-2-carbaldehyde and 4-benzoylpyridine, in which substituent interactions with metal or halide are insufficient to destroy the basic polymer form but nevertheless may induce substantial distortions from the orthogonal ideal. 
ER  -

