
%0 Journal Article
%A Healy, PC 
%A Kildea, JD 
%A White, AH 
%T Lewis-Base Adducts of Group 11 Metal(I) Compounds. XLIV. Synthesis and Conformational Systematics of 1 : 1 Copper(I) Halide Nitrogen Base Adducts as [(N-base)CuX<sub>2</sub>Cu(N-base)] Dimers (X = Cl, Br, I) and [(N-Base)CuX] Monomers (X = Cl, Br)
%J Australian Journal of Chemistry
%D 1989/01/01
%V 42
%N 1
%P 137-148
%K 
%R https://doi.org/10.1071/CH9890137
%U https://www.publish.csiro.au/paper/CH9890137 
%X A complete array of [LcuX2CuL] dimers for the system CuX/monodentate nitrogen base, L, all X = Cl, Br, I, has been synthesized and structurally characterized for the highly hindered pyridine base L &#8776; 1,2,3,4,5,6,7,8-octahydroacridine, enabling comparison of stereochemical parameters with previously characterized [L2CuX2CuL2] arrays (L monodentate ). With L-2,2,6,6-tetramethylpiperidine, a similar dimer is also obtained with copper(I) iodide, but with the chloride and bromide adducts linear monomers [ LCuX ] have been obtained, the first to be structurally characterized for the copper(I) halide/nitrogen base system. In the latter Cu-Cl, Br are 2.087(2) and 2.216(2), 2.202(2) A, Cu-N being 1.923(3) and 1.931(9), 1.9337) Å . 
