
TY  - JOUR
A1  - Engelhardt, LM 
A1  - Patrick, JM 
A1  - White, AH 
T1  - Lewis-Base Adducts of Lead(II) Compounds. III. Synthesis and Structural Characterization of Mononuclear (Nitrato-O,O&#8242;)bis(1,10-phenanthroline)-(thiocyanato-N)lead(II)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1989
VL  - 42
IS  - 2
SP  - 335
EP  - 338
KW  - 
UR  - https://doi.org/10.1071/CH9890335 
N2  - The isolation and single-crystal X-ray structure determination of the title compound, [(phen)2Pb(NCS)(O2NO)] is described; crystals are triclinic, P1, a 15.554(7), b 9-670(4), c 8.429(3) &#945; 72.53(3), &#946; 81.90(3), &#947; 72.88(3)º Z = 2, yielding R 0.052 for 3405 independent 'observed' reflections. The lead atom is seven-coordinate [Pb-N 2.49(1)-2.60(1) (phen), 2.89(1) (NCS); Pb-O 2.75(1), 2.89(1) Å] with a large vacancy in the coordination sphere, possibly indicative of a stereochemically active lone pair. 
ER  -

