
%0 Journal Article
%A Ohair, RAJ 
%A Sheldon, JC 
%A Bowie, JH 
%A Damrauer, R 
%A Depuy, CH 
%T Gas-Phase Ion Chemistry of Siloxide and Silamide Ions by Using the Flowing Afterglow. Unusual Rearrangements Involving SiO and SiS Bond Formation
%J Australian Journal of Chemistry
%D 1989/04/01
%V 42
%N 4
%P 489-496
%K 
%R https://doi.org/10.1071/CH9890489
%U https://www.publish.csiro.au/paper/CH9890489 
%X Siloxide ions undergo O/S exchange reactions with suitable sulfur-containing neutrals, e.g. H3SiO-+CS2 &#8594; H3SiS-+COS. Silamide ions similarly undergo NR/O and NR/S exchange reactions together with nucleophilic displacement reactions, e.g. Me3SiNMe + CO2 &#8594; Me3SiO-+MeNCO &#8594;No simple correlation between rate and mechanism is observed for all the studied reactions. 
