
TY  - JOUR
A1  - Ohair, RAJ 
A1  - Sheldon, JC 
A1  - Bowie, JH 
A1  - Damrauer, R 
A1  - Depuy, CH 
T1  - Gas-Phase Ion Chemistry of Siloxide and Silamide Ions by Using the Flowing Afterglow. Unusual Rearrangements Involving SiO and SiS Bond Formation
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1989
VL  - 42
IS  - 4
SP  - 489
EP  - 496
KW  - 
UR  - https://doi.org/10.1071/CH9890489 
N2  - Siloxide ions undergo O/S exchange reactions with suitable sulfur-containing neutrals, e.g. H3SiO-+CS2 &#8594; H3SiS-+COS. Silamide ions similarly undergo NR/O and NR/S exchange reactions together with nucleophilic displacement reactions, e.g. Me3SiNMe + CO2 &#8594; Me3SiO-+MeNCO &#8594;No simple correlation between rate and mechanism is observed for all the studied reactions. 
ER  -

