
TY  - JOUR
A1  - Eichinger, PCH 
A1  - Bowie, JH 
A1  - Hayes, RN 
T1  - Stable Negative-Ion Isomers in the Gas Phase. C<sub>7</sub>H<sub>7</sub>O<sup>-</sup> Species
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1989
VL  - 42
IS  - 6
SP  - 865
EP  - 874
KW  - 
UR  - https://doi.org/10.1071/CH9890865 
N2  - The C7H7O- ions formed by deprotonation of benzyl alcohol, norbornadien-7-ol and quadricyclin-7-ol are discrete species which all fragment by competitive losses of H, H2, CH2O and C6H6 on collisional activation. The isomeric ion from norbornen-2-one behaves differently undergoing retro cleavage to form HC2O- and C5H5- as product ions. The three deprotonated cresols are also distinct species. Anisole is deprotonated (by amide ion) to form both PhOCH2- and (C6H4)-OMe, ions which equilibrate prior to elimination of formaldehyde. 
ER  -

