
%0 Journal Article
%A Engelhardt, LM 
%A Healy, PC 
%A Kildea, JD 
%A White, AH 
%T Lewis-Base Adducts of Group 11 Metal(I) Compounds. LVI. Structural Characterization of &#956;,&#956;&#8242;-Dibromo-bis[(acetonitrile)(diphenyl-o-tolyl-phosphine)copper( I)] Bis(acetonitrile)
%J Australian Journal of Chemistry
%D 1989/06/01
%V 42
%N 6
%P 945-947
%K 
%R https://doi.org/10.1071/CH9890945
%U https://www.publish.csiro.au/paper/CH9890945 
%X The title compound, [((2-MeC6H4)Ph2P)( MeCN )CuBr2Cu( MeCN )(PPh2-MeCH)]2MeCN has been isolated in the course of recrystallization of a 1 : 1 stoichiometric ratio of copper(]) bromide and the phosphine ligand from acetonitrile and characterized by a single-crystal X-ray structure determination. Crystals are triclinic, PI, a 13.148(2), b 10.673(2), c 8.101(1) Å , &#945; 84.24(4), &#946; 89.42(4), &#947; 82.02(2)&#176;, Z= 1 dimer ; R was 0.050 for 1772 independent 'observed' reflections. The dimer is centrosymmetric and is the first 1 : 1 : 1 mixed base copper(1) halide : phosphine : nitrile adduct to be so isolated and so characterized. 
