
%0 Journal Article
%A Clegg, DE 
%A Healy, PC 
%A Patch, GJ 
%A Skelton, BW 
%A White, AH 
%T Structural Characterization of the Reaction Products of Vanadium(II) and Endrin as 2 Isomers of 1,8,<I>exo</I>-9,10,11-Pentachloropentacyclo[6.2.1.1<sup>3,6</sup>.0<sup>2,7</sup>.0<sup>4,10</sup>]dodecan-5-one
%J Australian Journal of Chemistry
%D 1989/06/01
%V 42
%N 6
%P 959-963
%K 
%R https://doi.org/10.1071/CH9890959
%U https://www.publish.csiro.au/paper/CH9890959 
%X Two dechlorinated products (B) and (D), formed in the reaction between endrin (C12H8Cl6O) and vanadium(II) for the purpose of confirmation of identity, are shown by single-crystal X-ray structure determination to be isomers of the title compound, C12H9Cl5O. Crystals of both are monoclinic, P21/c. For isomer (B), a 7.432(8), b 12.76(1), c 14.55(2) Å , &#946; 108.32(9)º, Z=4; R was 0.038 for 2594 observed reflections. For isomer (D), a 9.037(4), b 12.004(4), c 14.436(6) Å , &#946; 124.91(2)&#176;, Z= 4; R was 0.041 for 1826 reflections. The geometries of the two isomers are compared. 
