
TY  - JOUR
A1  - Clegg, DE 
A1  - Healy, PC 
A1  - Patch, GJ 
A1  - Skelton, BW 
A1  - White, AH 
T1  - Structural Characterization of the Reaction Products of Vanadium(II) and Endrin as 2 Isomers of 1,8,<I>exo</I>-9,10,11-Pentachloropentacyclo[6.2.1.1<sup>3,6</sup>.0<sup>2,7</sup>.0<sup>4,10</sup>]dodecan-5-one
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1989
VL  - 42
IS  - 6
SP  - 959
EP  - 963
KW  - 
UR  - https://doi.org/10.1071/CH9890959 
N2  - Two dechlorinated products (B) and (D), formed in the reaction between endrin (C12H8Cl6O) and vanadium(II) for the purpose of confirmation of identity, are shown by single-crystal X-ray structure determination to be isomers of the title compound, C12H9Cl5O. Crystals of both are monoclinic, P21/c. For isomer (B), a 7.432(8), b 12.76(1), c 14.55(2) Å , &#946; 108.32(9)º, Z=4; R was 0.038 for 2594 observed reflections. For isomer (D), a 9.037(4), b 12.004(4), c 14.436(6) Å , &#946; 124.91(2)&#176;, Z= 4; R was 0.041 for 1826 reflections. The geometries of the two isomers are compared. 
ER  -

