
TY  - JOUR
A1  - Patroni, JJ 
A1  - Stick, RV 
A1  - Tilbrook, DMG 
A1  - Skelton, BW 
A1  - White, AH 
T1  - The Synthesis and Reactivity of Cyclic Thiocarbonates Derived From Some Carbohydrate 1,2-Diols
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1989
VL  - 42
IS  - 12
SP  - 2127
EP  - 2141
KW  - 
UR  - https://doi.org/10.1071/CH9892127 
N2  - The attempted synthesis of several carbohydrate 1,2-diols is reported, together with the transformation of two of these diols into cyclic thiocarbonates, namely 4,6-O-benzylidene-3-O-methyl-1,2-O-thiocarbonyl-a-D-glucose and 3,4-O-isopropylidene-1,2-O-thiocarbonyl-&#946;-D-arabinose. The treatment of these thiocarbonates, and a furanose 1,2-thiocarbonate previously prepared by Mukaiyama, with methyl halides and with tributyltin hydride is discussed. A single-crystal X-ray diffraction study of 3,4-O-isopropylidene-1,2-O-thiocarbonyl-&#946;-D-arabinose is recorded. 
ER  -

