
%0 Journal Article
%A Ainscough, Eric W. 
%A Brodie, Andrew M. 
%A Coll, Richard K. 
%A Waters, Joyce M. 
%T The Interaction of Triosmium Clusters with Pyridinethiols: the Crystal and Molecular Structures of [{Os<emph type="8">3</emph>(<emph type="2">&#181;</emph>-H)(CO)<emph type="8">10</emph>}<emph type="8">2</emph>(<emph type="2">&#181;</emph>-S<emph type="8">2</emph>C<emph type="8">4</emph>H<emph type="8">2</emph>N<emph type="8">2</emph>)]and [Os<emph type="8">3</emph>(<emph type="2">&#181;</emph>-H)(CO)<emph type="8">10</emph>(<emph type="2">&#181;</emph>-SC<emph type="8">5</emph>H<emph type="8">4</emph>N)]
%J Australian Journal of Chemistry
%D 1999/08/27
%V 52
%N 8
%P 801-806
%K 
%R https://doi.org/10.1071/CH99002
%U https://www.publish.csiro.au/paper/CH99002 
%X Pyrimidine-2,4-dithiol &#91;HL 1 = (HS)2C4H2N2&#93; and pyridine-2-thiol &#91;HL 2 = (HS)C5H4N&#93; form the osmium clusters &#91;&#123;Os3(&#181;-H)(CO)10&#125;2(&#181;-S2C4H2N2)&#93; and &#91;Os3(&#181;-H)(CO)10(&#181;-SC5H4N)&#93;, each of which contain chelating &#181;,&#951;1-thiolate ligands and hydride bridges across common edges of the osmium triangles. In the former complex two osmium triangles are linked together by the pyrimidinedithiolato ligand. 
