
TY  - JOUR
A1  - Smolik, Marek 
T1  - Partition of Microamounts of Some M<emph type="7">2+</emph> Ions During MgSO<emph tye="8">4</emph>.7H<emph tye="8">2</emph>O Crystallization
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1999
VL  - 52
IS  - 6
SP  - 425
EP  - 430
KW  - 
UR  - https://doi.org/10.1071/CH99011 
N2  - Partition coefficients (D) of trace amounts of Ni2+, Co2+, Zn2+, Cd2+, Cu2+, Mn2+, Ca2+, and Fe2+ have been determined during crystallization of MgSO4.7H2O. Their dependences on the ionic radii of the M2+ ions, solubilities and structures of the corresponding sulfates, as well as the abilities of the microcomponents to form solid solutions with MgSO4.7H2O have been analysed. The D values are in the range from &#60;0&#183;005 (DCa) to 1&#183;13 (DNi) and depend mainly on the ionic radii of the M2+ ions, as well as the structures of the corresponding sulfates and the ability to form solid solutions with the macrocomponent. 
ER  -

