
TY  - JOUR
A1  - Stick, RV 
A1  - Tilbrook, DMG 
T1  - The Synthesis of Some Octenoses as Potential Precursors to Lincosamine, a Derived Portion of the Antibiotic Lincomycin
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1990
VL  - 43
IS  - 10
SP  - 1643
EP  - 1655
KW  - 
UR  - https://doi.org/10.1071/CH9901643 
N2  - Methyl (E)-2,3-di-O-benzyl-6,7,8-trideoxy-&#945;-D-galacto-oct-6-enopyranoside, a potential precursor to lincosamine, has been prepared from both methyl &#945;-D-galactopyranoside and methyl &#945;-D-glucopyranoside, with the required inversion at C4 in the latter sequence being effected by a conventional oxidation-reduction. As well, (E)-6,7-dideoxy-1,2: 3,4-di-O-isopropylidene-&#945;-D-galacto-oct-6-enose and (E)- and (Z)-6,7,8- trideoxy-1,2:3,4-di-O-isopropylidene-&#945;-D-galacto-oct-6-enose have been prepared from 1,2: 3,4-di-O-isopropylidene-&#945;-D-galactose. 
ER  -

