
TY  - JOUR
A1  - Alexander, MJ 
A1  - Bowie, JH 
A1  - Hayes, RN 
T1  - The Collision-Induced Dissociations of Deprotonated Isopropyl and t-Butyl Ketones. Some Unusual Alkyl Migrations
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1990
VL  - 43
IS  - 12
SP  - 2027
EP  - 2034
KW  - 
UR  - https://doi.org/10.1071/CH9902027 
N2  - Rearrangement reactions involving hydride and methyl anion migrations are observed when certain enolate ions derived from isopropyl and t- butyl ketones are subjected to collisional activation. For example (i) -CH2CO-i-C3H7 &#8594; -(CH2CHO)+C3H6 and  (ii) -CH2CO-t-C4H9 &#8594; -(CH2COCH3)+C3H6The mechanisms of these and related reactions have been investigated by denterium labelling and product ion studies. 
ER  -

