
%0 Journal Article
%A Bowmaker, GA 
%A Effend, y 
%A Kildea, JD 
%A Skelton, BW 
%A White, AH 
%T Mixed-Halide Iodoargentate Anions: the Structural Characterization of (Ag<sub>3</sub>I<sub>3</sub>X)<sup>-</sup>, X= Cl, Br, I
%J Australian Journal of Chemistry
%D 1990/12/01
%V 43
%N 12
%P 2113-2117
%K 
%R https://doi.org/10.1071/CH9902113
%U https://www.publish.csiro.au/paper/CH9902113 
%X Single-crystal structure determinations are recorded for [Ph3AsMe]+ [Ag3I3X]-, X= Cl , Br, I. The three complexes are isomorphous with their recently recorded [Cu3I4]- counterpart. They are also 'isomorphous' with the recently recorded [Ph4P/As]+ [Ag3I4]-, crystallizing in a monoclinic P21/c cell with a &#8776; 12.5 , b &#8776; 25.6, c &#8776; 8.39&#506;, &#946; &#8776; 109&#176;, Z=4 formula units. The anion is an infinite polymer with three distinct metal and four distinct halide sites; the mixed stoichiometry is achieved by displacement of the peripheral halide species. 
