
TY  - JOUR
A1  - Bowmaker, GA 
A1  - Effend, y 
A1  - Kildea, JD 
A1  - Skelton, BW 
A1  - White, AH 
T1  - Mixed-Halide Iodoargentate Anions: the Structural Characterization of (Ag<sub>3</sub>I<sub>3</sub>X)<sup>-</sup>, X= Cl, Br, I
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1990
VL  - 43
IS  - 12
SP  - 2113
EP  - 2117
KW  - 
UR  - https://doi.org/10.1071/CH9902113 
N2  - Single-crystal structure determinations are recorded for [Ph3AsMe]+ [Ag3I3X]-, X= Cl , Br, I. The three complexes are isomorphous with their recently recorded [Cu3I4]- counterpart. They are also 'isomorphous' with the recently recorded [Ph4P/As]+ [Ag3I4]-, crystallizing in a monoclinic P21/c cell with a &#8776; 12.5 , b &#8776; 25.6, c &#8776; 8.39&#506;, &#946; &#8776; 109&#176;, Z=4 formula units. The anion is an infinite polymer with three distinct metal and four distinct halide sites; the mixed stoichiometry is achieved by displacement of the peripheral halide species. 
ER  -

