
TY  - JOUR
A1  - Kadirvelraj, Renuka 
A1  - Handley, Paul N. 
A1  - Robinson, Ward T. 
A1  - Carman, Raymond M. 
A1  - Sutherland, Maurice D. 
T1  - The Stereochemical Structures of the Furanosesquiterpenoidal <emph type="2">&#946;</emph>-Hydroxy Ketones from the Myoporaceae
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1999
VL  - 52
IS  - 8
SP  - 727
EP  - 732
KW  - 
UR  - https://doi.org/10.1071/CH99045 
N2  - Four furanosesquiterpene &beta;-hydroxy ketones previously isolated from Myoporum spp., and given tentative names, are now assigned complete stereostructures from n.m.r. and X-ray data. The compounds are (5R,7R,9S)-9-hydroxy-5,9-dihydromyomontanone (Woogaroo) (1a), (5S,7R,9R)-9-hydroxy-5,9-dihydro- myomontanone (Redbank) (1b), (5R,7R,9R)-9-hydroxy-5,9-dihydromyomontanone (Perillup) (1c) and (4S,7S,8R)-4-hydroxy-10,11-didehydro-4,8-dihydromyodesmone (Carney's ketol) (2a). The stereo- structures of two other previously reported compounds, Kindon ketol ((4S,7S,8R)-4-hydroxy-4,8- dihydromyodesmone) (2b), and Carr's ketol ((4S,7S,8S)-4-hydroxy-4,8-dihydromyodesmone) (2c), follow from the above results. 
ER  -

