
%0 Journal Article
%A Elsworth, Catherine 
%A Gill, Melvyn 
%A Milanovic, Nives M. 
%T Pigments of Fungi. LV. The Absolute Configuration of Dermocanarin 4 and the Structure and Stereochemistry of the Dermocanarins 5, 6, 8 and 9 from Australian Toadstools Belonging to the Genus <emph type="2">Cortinarius</emph>
%J Australian Journal of Chemistry
%D 1999/11/11
%V 52
%N 9
%P 867-874
%K 
%R https://doi.org/10.1071/CH99076
%U https://www.publish.csiro.au/paper/CH99076 
%X The stereochemistry in the dihydroanthracenone ring of dermocanarin 4 (1) is defined as (S) by incorporation of the gentiobioside (2) of (S)-&#91;6-OMe- 13 C&#93;torosachrysone into the dihydroanthracenone ring of dermocanarin 4 by fruiting bodies of Cortinarius sinapicolor. In addition, the new dermocanarins 5 (3), 6 (4), 8 (5) and 9 (6) are isolated from two other indigenous toadstools belonging to Cortinarius and their structure and stereochemistry are deduced from the respective spectroscopic data and by comparison with dermocanarin 4 (1). 
