
TY  - JOUR
A1  - Elsworth, Catherine 
A1  - Gill, Melvyn 
A1  - Milanovic, Nives M. 
T1  - Pigments of Fungi. LV. The Absolute Configuration of Dermocanarin 4 and the Structure and Stereochemistry of the Dermocanarins 5, 6, 8 and 9 from Australian Toadstools Belonging to the Genus <emph type="2">Cortinarius</emph>
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1999
VL  - 52
IS  - 9
SP  - 867
EP  - 874
KW  - 
UR  - https://doi.org/10.1071/CH99076 
N2  - The stereochemistry in the dihydroanthracenone ring of dermocanarin 4 (1) is defined as (S) by incorporation of the gentiobioside (2) of (S)-&#91;6-OMe- 13 C&#93;torosachrysone into the dihydroanthracenone ring of dermocanarin 4 by fruiting bodies of Cortinarius sinapicolor. In addition, the new dermocanarins 5 (3), 6 (4), 8 (5) and 9 (6) are isolated from two other indigenous toadstools belonging to Cortinarius and their structure and stereochemistry are deduced from the respective spectroscopic data and by comparison with dermocanarin 4 (1). 
ER  -

