
TY  - JOUR
A1  - Kemmitt, Tim 
A1  - Al-Salim, Najeh I. 
A1  - Gainsford, Graeme J. 
A1  - Henderson, William 
T1  - Titanium Amino Alcohol Complexes from &#945;-Titanic Acid: X-Ray Crystal Structure of Titanium Bis[2,2&acute;-(methylimino)diethanolate]
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1999
VL  - 52
IS  - 10
SP  - 915
EP  - 920
KW  - 
UR  - https://doi.org/10.1071/CH99089 
N2  - A method for producing amino alcohol complexes of titanium from hydrated titania (&#945;-titanic acid) is described. Thus hydrated titania was completely converted into triethanolamine and diethanolamine complexes during reaction at 120&#176;C for 6 h. This represents a synthetic method for titanium sol&#8211;gel precursors which are free from chlorine-containing impurities. Products were characterized with assistance from 1 H and 13 C nuclear magnetic resonance spectroscopy, and electrospray mass spectrometry. A single-crystal X-ray structure of titanium bis&#91;2,2&acute;- (methyl-imino)ethanolate&#93;, tetragonal, space group P4 &#8211; 2 1 c, is presented. The titanium centre is coordinated by an N2O4 donor set which can be most closely described as a bifacially capped tetrahedral geometry. 
ER  -

