
TY  - JOUR
A1  - Bartnicka, H 
A1  - Bojanowska, I 
A1  - Kalinowski, MK 
T1  - Solvent Effect on the Dissociation Constants of Aliphatic Carboxylic Acids
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1991
VL  - 44
IS  - 8
SP  - 1077
EP  - 1084
KW  - 
UR  - https://doi.org/10.1071/CH9911077 
N2  - Dissociation constants of 10 aliphatic carboxylic acids, of general formula R-COOH, were measured by potentiometric titration in acetonitrile, propylene carbonate, acetone, N,N- dimethylformamide and dimethyl  sulfoxide. The p* reaction constants of the Taft equation were found to depend on the solvent polarity, whereas the influence of the Lewis basicity and acidity is negligible. The p* values determined earlier in water, methanol and nitromethane also fulfil this rule. 
ER  -

