
%0 Journal Article
%A Kaya, Tuncer 
%T Modified Linearized Poisson-Boltzmann Theory. Dynamic and Thermodynamic Properties of 1 : 1 Electrolytes
%J Australian Journal of Chemistry
%D 2001/05/11
%V 53
%N 12
%P 989-994
%K Poisson&#8211;Boltzmann theory; activity coefficient; osmotic pressure
%R https://doi.org/10.1071/CH99132
%U https://www.publish.csiro.au/paper/CH99132 
%X Theoretical electrolyte conductivity and osmotic and activity coefficient relationships that work well over a large range of concentrations, up to 1 mol l&#8211;1, are derived from a hypothetical modified linearized Poisson&#8211;Boltzmann distribution function. The distribution function is expressed in terms of modified Debye parameter &kgr; and normalization constant &#945;. Both of these parameters are evaluated in terms of concentration and ion-size parameter, d, by the help of moment conditions. The modified Debye parameter &kgr; is also expressed as a function of the usual Debye parameter &kgr;D. Also considered is the short-range part of the pair potential crucial to obtain at least qualitative agreement with experimental results of electrolytic solutions, and it is assumed that the short-range part of the potential is discontinuous at ion-size parameter 
