
TY  - JOUR
A1  - Liu, Wei 
A1  - Jiang, Jianzhuang 
A1  - Du, Daming 
A1  - Arnold, Dennis P. 
T1  - Synthesis and Spectroscopic Properties of Homoleptic Bis[octakis(octyloxy)phthalocyaninato] Rare Earth(III) Sandwich Complexes
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 2000
VL  - 53
IS  - 2
SP  - 131
EP  - 135
KW  - Anion radical; lanthanide; lanthanoid; phthalocyanine; Soret band.
UR  - https://doi.org/10.1071/CH99168 
N2  - A series of homoleptic bis&#91;2,3,9,10,16,17,23,24-octakis(octyloxy)phthalocyaninato&#93; rare earth(III) sandwich complexes &#123;M&#91;Pc(OC8H17)8&#93;2 (M = La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Y, Ho, Er, Tm) (1) and (3)&#8211;(13), and HCe&#91;Pc(OC8H17)8&#93;2 (2)&#125; has been prepared by the cyclic tetramerization of 4,5-di(octyloxy)phthalonitrile on the template of M(acac)3&#183;nH2O in the presence of 1,8-diazabicyclo&#91;5.4.0&#93;undec-7-ene. Their spectroscopic properties were systematically investigated by ultraviolet&#8211;visible, near-infrared, infrared, and mass spectroscopy, and the effects of ionic radius on the inter-ring electronic communication are described. 
ER  -

