
%0 Journal Article
%A Di Florio, Romina 
%A Rizzacasa, Mark A. 
%T Synthesis of the Syributins and Formal Total Synthesis of Syringolide 1.
%J Australian Journal of Chemistry
%D 2000/07/21
%V 53
%N 4
%P 327-331
%K Amberlyst 15; butenolide; glyceraldehyde acetonide; synthesis; syributin; syringolide.
%R https://doi.org/10.1071/CH99170
%U https://www.publish.csiro.au/paper/CH99170 
%X A synthesis of syributins 1 (5) and 2 (6) from D-glyceraldehyde acetonide (12) and furans (14) and (15) is described. Compounds (5) and (6) are cometabolites of the novel non-proteinaceous C-glycosidic elicitor molecules the syringolides 1 (1) and 2 (2). Under a variety of acidic conditions, the intermediate butenolides (9) and (10) provided syributins 1 (5) and 2 (6). Similar results have been reported by Honda and coworkers who converted butenolide (20) into syringolide 1 (1). Since compound (20) was also synthesized by the present new route, a formal synthesis of syringolide 1 (1) has been achieved. 
