
%0 Journal Article
%A Hartshorn, RM 
%A Sargeson, AM 
%T Reactions of Chelated &#946;-Functionalized Amino Acids With Thionyl Chloride
%J Australian Journal of Chemistry
%D 1992/01/01
%V 45
%N 1
%P 5-20
%K 
%R https://doi.org/10.1071/CH9920005
%U https://www.publish.csiro.au/paper/CH9920005 
%X A variety of bis (ethane-1,2-diamine)cobalt(III) complexes containing chelated  &#946;-functionalized amino acids have been treated with SOCl2 in dimethylformamide. These compounds undergo &#946;-elimination reactions to give chelated enamines followed by either rearrangement to the related imine complexes or further reactions with SOCl2 to give chelated isothiazole-3-carboxylato complexes. Mechanisms are proposed for the reactions. 
