
%0 Journal Article
%A Canty, AJ 
%A Minchin, NJ 
%A Skelton, BW 
%A White, AH 
%T The Structure of [PdCl<sub>2</sub>{(Py)<sub>2</sub>(PyH)CH-N&#8242;,N&#8243;}][PdCl<sub>4</sub>]<sub>0.5</sub>.2H<sub>2</sub>O (Py = Pyridin-2-yl), a Complex With Protonated 2,2&#8242;,2&#8243;-Methylidynetrispyridine as a Bidentate Ligand
%J Australian Journal of Chemistry
%D 1992/02/01
%V 45
%N 2
%P 423-427
%K 
%R https://doi.org/10.1071/CH9920423
%U https://www.publish.csiro.au/paper/CH9920423 
%X Crystals of dichloro[2,2&#8242;,2&#8243;-methylidynetris(pyridin)-1-ium-N&#8242;,N&#8243;]palladium(II) hemi[tetra-chloropalladate(II)] dihydrate are monoclinic, P21/c, a 8.558(5), b 15.516(7), c 16.153(5) a, P 112.07(4)&#176;, Z 4. The cations [PdCl2{(Py)2(PyH)CH-N&#8242;,N&#8243;}]+ have square-planar geometry for palladium, with the ligand in a boat conformation and having an uncoordinated protonated pyridine group. 
