
%0 Journal Article
%A Baker, AT 
%A Emett, MT 
%T The Crystal and Molecular Structures of Bis(diethyldithiocarbamato)platinum(II) and Bis[di(2-hydroxyethyl)dithiocarbamato]platinum(II)
%J Australian Journal of Chemistry
%D 1992/02/01
%V 45
%N 2
%P 429-434
%K 
%R https://doi.org/10.1071/CH9920429
%U https://www.publish.csiro.au/paper/CH9920429 
%X The structures of [Pt(S2CN(C2H5)2)2] (1) and [Pt(S2CN(C2H4OH)2)2] (2) have been determined by single-crystal X-ray diffractometry. Compound (1) crystallizes in the tetragonal space group P42/n, a 16.4692(10),c 6.2160(6) Å (Z = 4); R was 0.029 for 1012 observed reflections. Compound (2) is monoclinic, space group Pc, a 6-0663(11), b 1.1784(15), c 12.5740(21) Å ,&#946;92.569(8)º (Z = 2); R was 0.019 for 1573 observed reflections. The presence of electron-withdrawing groups in the ligands of (2) appears to have little effect on the Pt-S distances but causes an increase in the C-N bond length, with the C-N bond lengths being significantly different at the 2 &#963; level. 
