
TY  - JOUR
A1  - Chow, MY 
A1  - Mak, TCW 
T1  - A Mononuclear Cobalt(II) Complex Containing Pyridine Betaine and Thiocyanate Ligands: Triaquabis(pyridinioacetato-O)(thiocyanato-N)cobalt(1+) Tetra(thiocyanato-N)cobaltate(2-)
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1992
VL  - 45
IS  - 8
SP  - 1307
EP  - 1313
KW  - 
UR  - https://doi.org/10.1071/CH9921307 
N2  - The cobalt(II) complex [Co(C5H5NCH2CO2)2(NCS)(H2O)3]2 [Co(NCS)4] has been synthesized, and characterized by X-ray crystallography. The complex comprises distorted octahedral [CO(C5H5NCH2CO2)2(NCS)(H2O)3]+ cations, in which the cobalt atom is surrounded by two trans monodentate pyridine betaine ligands, one N-bonded thiocyanate ligand and three aqua ligands, as well as distorted tetrahedral [CO(NCS)4]2- anions. Two-thirds of the aqua ligands form intra- and inter-molecular hydrogen bonds with the coordinated and uncoordinated carboxylate oxygens , linking the cations into a one-dimensional polymeric block directed along a 21 axis. 
ER  -

