
%0 Journal Article
%A Anastasiou, D 
%A Campi, EM 
%A Fallon, GD 
%A Jackson, WR 
%T Reassignment of the Compounds Reported to be 4,5-Dihydro-3H-1-benzazepin-5-ols as 2,3,4,5-Tetrahydro-2,5-epoxy-1H-1-benzazepines and 3,4,5,6-Tetrahydro-1,6-benzodiazocines as 2,3,3a,4-Tetrahydro-1H-pyrrolo[1,2-a]benzimidazoles
%J Australian Journal of Chemistry
%D 1993/10/01
%V 46
%N 10
%P 1623-1627
%K 
%R https://doi.org/10.1071/CH9931623
%U https://www.publish.csiro.au/paper/CH9931623 
%X Reexamination of the 1H and 13C n.m.r. spectra of the supposed 4,5-dihydro-3H-1-benzazepin-5-ols (1) has led to a reassignment of their structure as 2,3,4,5-tetrahydro-2,5-epoxy-1H-1-benzazepines (3) and the new structure has been confirmed by a single-crystal X-ray structure determination of the 5-phenyl derivative (3; R1 = H, R2 = Ph). Similar examination of the n.m.r. spectra of the supposed 3,4,5,6-tetrahydro-1,6-benzodiazocines (2) has led to their reassignment as the pyrrolo [1,2-a] benzimidazoles (4). 
