
TY  - JOUR
A1  - Golka, A 
A1  - Craig, DC 
A1  - Paddonrow, MN 
T1  - Crystal Structure of a Bis(2,2'-bipyridine)ruthenium(II) Complex of a Dimethoxynaphthalene-Norbornyl-Pyridazine Ligand
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1994
VL  - 47
IS  - 1
SP  - 101
EP  - 110
KW  - 
UR  - https://doi.org/10.1071/CH9940101 
N2  - The bis (2,2&#8242;-bipyridine)(6,11-dimethoxy-1,4-di(2&#8242;-pyridyl)-5,12-dihydro-5,12-methanonaphtho-[2,3-g] phthalazine )ruthenium(II) complex exists in two diastereomeric forms, (3a) and (3b). In order to make an unambiguous assignment of the configuration of each stereoisomer, a single-crystal X-ray structure of the hexafluorophosphate salt of the less soluble isomer (in methanol/acetone) was carried out. It was found that the structure of this material corresponded to (3a). Differences in he 1H n.m.r. spectra of (3a) and (3b) are discussed in light of their structures. 
ER  -

