
TY  - JOUR
A1  - Bharadwaj, PK 
A1  - Lee, AM 
A1  - Skelton, BW 
A1  - Srinivasan, BR 
A1  - White, AH 
T1  - Single Crystal X-Ray Structural Characterization of [BiX<sub>2</sub>(S<sub>2</sub>CNEt<sub>2</sub>)]Infinity&#8734;, X=Cl, Br
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1994
VL  - 47
IS  - 2
SP  - 405
EP  - 410
KW  - 
UR  - https://doi.org/10.1071/CH9940405 
N2  - Single-crystal room-temperature X-ray structure determinations of the title compounds have been carried out. The two compounds are isomorphous, and isomorphous with the previously determined iodide analogue, being monoclinic, P 21/c, a &#8776; 10.0, b &#8776; 14.9, c &#8776; 7.8 &#506;, &#946; &#8776; 92&#176;, Z = 4 formula units; residuals were 0.037, 0.036 for 2197, 1654 'observed' reflections for X = Cl , Br respectively. As in the iodide, the complexes are infinite polymers, with successive bismuth atoms bridged by the two halides and one sulfur atom of the ligand , which also chelates each bismuth. The structure determination of C5H5NCONEt2]2 [Cl5Bi(NC5H5)], isostructural with its thiocarbamoyl analogue, is also recorded. 
ER  -

