
%0 Journal Article
%A Bruce, MI 
%A Humphrey, PA 
%A Surynt, RJ 
%A Tiekink, ERT 
%T Cluster Chemistry. XCV. Some More Chemistry of Ru<sub>3</sub>(&#956;-dppm )(CO)<sub>10</sub>: Reactions With Allyl Bromide, Dimethyl Disulfide and AuCl(PPh<sub>3</sub>), and Preparation of Some Complexes Containing Tertiary Phosphines and Phosphites. X-Ray Structure of Ru<sub>3</sub>(&#956;-H)(&#956;-SMe)(&#956;-dppm)(CO)<sub>8</sub>
%J Australian Journal of Chemistry
%D 1994/03/01
%V 47
%N 3
%P 477-486
%K 
%R https://doi.org/10.1071/CH9940477
%U https://www.publish.csiro.au/paper/CH9940477 
%X Reactions between Ru3(&#956;-dppm )(CO)10 and several reagents have been studied. With allyl bromide, cluster breakup occurs to give binuclear Ru2(&#956;-Br)(&#956;-C3H5)(&#956;- dppm )(CO)4. With Me2S2, binuclear Ru2(&#956;- SMe )2(&#956;- dppm )(CO)4 and trinuclear Ru3(&#956;-H)(&#956;- SMe )(&#956;- dppm )(CO)8 are obtained; the X-ray structure of the latter has been determined. With AuCl (PPh3), addition to one Ru-Ru bond gives AuRu3(&#956;- Cl )(&#956;- dppm )(CO)8(PPh3). Some data on tertiary phosphine substituted products formed in reactions with PMe3, PPh3, P(C6H4Me-3)3, P(C6H4Me-4)3, P( OMe )3, P(OCH2CF3)3, dppe and Fe(&#951;-C5H4PPh2)2 are also given. 
