
TY  - JOUR
A1  - Butts, CP 
A1  - Calvert, JL 
A1  - Eberson, L 
A1  - Hartshorn, MP 
A1  - Maclaga, n 
A1  - Robinson, WT 
T1  - Photochemical Nitration by Tetranitromethane. XIV. The Formation of 1,3-Dipolar Nitro Addition Products From the Photochemical Reaction of 1,2-Dimethylnaphthalene and Tetranitromethane
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1994
VL  - 47
IS  - 6
SP  - 1087
EP  - 1096
KW  - 
UR  - https://doi.org/10.1071/CH9941087 
N2  - Photolysis of the 1,2-dimethylnaphthalene/tetranitromethane charge-transfer complex yields the triad of 1,2-dimethylnaphthalene radical cation, nitrogen dioxide, and trinitromethanide ion. Recombination of this triad gives predominantly the adducts (13)-(16), each of which is formed by attack of the trinitromethanide ion at C4 of the 1,2-dimethylnaphthalene radical cation. Thermal cycloaddition in adducts (13) and (16) gives the cycloadducts (12) and (17) respectively. 
ER  -

