
TY  - JOUR
A1  - Smith, G 
A1  - Reddy, AN 
A1  - Byriel, KA 
A1  - Kennard, CHL 
T1  - The Crystal Structure of Silver(I) Glycolate Hemihydrate
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1994
VL  - 47
IS  - 6
SP  - 1179
EP  - 1183
KW  - 
UR  - https://doi.org/10.1071/CH9941179 
N2  - The silver(I) complex with glycolic acid, [Ag2(HOCH2CO2)2]n.nH2O, has been prepared and its structure determined by X-ray diffraction. The structure is based on a bis(carboxylato-O,O&#8242;) dimer [Ag-O, 2.234(2), 2.253(2) &#506;; Ag-Ag 2.8810(9)&#506;], extended in both the axial positions into a network polymer through two oxygens of a bidentate &#945;-hydroxy carboxy residue [Ag-O(hydroxy), 2.607(2) &#506;; Ag-O(carboxy), 2.456(2)&#506;; O-Ag-O, 63.45(5)&#8242;]. In this respect, the complex is unique among silver(I) carboxylate dimers. 
ER  -

