
%0 Journal Article
%A Kim, JH 
%A Craig, DC 
%A Gallagher, MJ 
%A Toia, RF 
%T Reaction of 2-Ethoxy-5-methyl-1,3,2-dioxaphosphorinane-5-methanol 2-Sulfide and 4-Methyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane 1-Sulfide With Sulfuryl Chloride: Mechanistic and Stereochemical Considerations
%J Australian Journal of Chemistry
%D 1994/12/01
%V 47
%N 12
%P 2161-2169
%K 
%R https://doi.org/10.1071/CH9942161
%U https://www.publish.csiro.au/paper/CH9942161 
%X Treatment of either cis- or trans-2-ethoxy-5-methyl-1,3,2,-dioxaphosphorinane-r-5-methanol 2-sulfide with SO2Cl2 yielded the cyclization product 4-methyl-2,6,7-trioxa-1-phosphabicyclo-[2.2.2]octane 1-oxide. In contrast, treatment of 4-methyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]-octane 1-sulfide with the same reagent gave stereospecific ring opening to trans-2-chloro-5-methyl-1,3,2-dioxaphosphorinane-r-5-methyl chloride 2-oxide. 
