
TY  - JOUR
A1  - Kim, JH 
A1  - Craig, DC 
A1  - Gallagher, MJ 
A1  - Toia, RF 
T1  - Reaction of 2-Ethoxy-5-methyl-1,3,2-dioxaphosphorinane-5-methanol 2-Sulfide and 4-Methyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane 1-Sulfide With Sulfuryl Chloride: Mechanistic and Stereochemical Considerations
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1994
VL  - 47
IS  - 12
SP  - 2161
EP  - 2169
KW  - 
UR  - https://doi.org/10.1071/CH9942161 
N2  - Treatment of either cis- or trans-2-ethoxy-5-methyl-1,3,2,-dioxaphosphorinane-r-5-methanol 2-sulfide with SO2Cl2 yielded the cyclization product 4-methyl-2,6,7-trioxa-1-phosphabicyclo-[2.2.2]octane 1-oxide. In contrast, treatment of 4-methyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]-octane 1-sulfide with the same reagent gave stereospecific ring opening to trans-2-chloro-5-methyl-1,3,2-dioxaphosphorinane-r-5-methyl chloride 2-oxide. 
ER  -

