
TY  - JOUR
A1  - Tomaszewski, MJ 
A1  - Warkentin, J 
A1  - Werstiuk, NH 
T1  - Free-Radical Chemistry of Imines
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1995
VL  - 48
IS  - 2
SP  - 291
EP  - 321
KW  - 
UR  - https://doi.org/10.1071/CH9950291 
N2  - Aryl radicals bearing an aldimino functional group as part of an ortho substituent cyclized by addition to C and/or N of the imino group. When the choice was between 5-exo closure to C and 6-endo closure to N, the former predominated. However, 6-endo closure to C predominated over 5-exo cyclization to N in isomeric imines. Absolute values of cyclization rate constants were determined and an explanation for the unusual 6-endo preference is offered. Chiral induction in 6-endo cyclization to C of an aldimine from D-glyceraldehyde acetonide was observed, and its sense was determined. 
ER  -

