
%0 Journal Article
%A Siasios, G 
%A Tiekink, ERT 
%T Preparation, Spectroscopic Characterization and X-Ray Structure of [Dicyclohexylphosphinyl-N-methyl(thioformamide)]gold(I) Chloride: Au[Cy<sub>2</sub>P(O)C(S)N(H)Me]Cl
%J Australian Journal of Chemistry
%D 1995/04/01
%V 48
%N 4
%P 757-762
%K 
%R https://doi.org/10.1071/CH9950757
%U https://www.publish.csiro.au/paper/CH9950757 
%X The reaction of [AuCl4]- with Cy2P(O)C(S)N(H)Me in the presence of thiodiglycol affords the air-stable adduct Au[Cy2P(O)C(S)N(H)Me] Cl which features a linear gold atom geometry defined by a chloride atom and a sulfur atom derived from a monodentate thioformamide  ligand. The pale-green crystals are monoclinic, space group P21, with unit cell dimensions a 18.507(4), b 12.204(2), c 18.513(6) &#506;, &#946; 117.69(2)&#176;, Z 8; the structure was refined to final R 0.042, 4106 reflections being used. 
