
TY  - JOUR
A1  - Siasios, G 
A1  - Tiekink, ERT 
T1  - Preparation, Spectroscopic Characterization and X-Ray Structure of [Dicyclohexylphosphinyl-N-methyl(thioformamide)]gold(I) Chloride: Au[Cy<sub>2</sub>P(O)C(S)N(H)Me]Cl
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1995
VL  - 48
IS  - 4
SP  - 757
EP  - 762
KW  - 
UR  - https://doi.org/10.1071/CH9950757 
N2  - The reaction of [AuCl4]- with Cy2P(O)C(S)N(H)Me in the presence of thiodiglycol affords the air-stable adduct Au[Cy2P(O)C(S)N(H)Me] Cl which features a linear gold atom geometry defined by a chloride atom and a sulfur atom derived from a monodentate thioformamide  ligand. The pale-green crystals are monoclinic, space group P21, with unit cell dimensions a 18.507(4), b 12.204(2), c 18.513(6) &#506;, &#946; 117.69(2)&#176;, Z 8; the structure was refined to final R 0.042, 4106 reflections being used. 
ER  -

