
%0 Journal Article
%A Varghese, AV 
%A Kalidas, C 
%A Singh, P 
%A Hefter, G 
%T Gibbs Transfer Energies and Solvent Transport Numbers of Some Copper(II) Salts in Methanol-Dimethylformamide Mixtures
%J Australian Journal of Chemistry
%D 1995/05/01
%V 48
%N 5
%P 987-996
%K 
%R https://doi.org/10.1071/CH9950987
%U https://www.publish.csiro.au/paper/CH9950987 
%X Standard Gibbs energies of transfer have been determined for copper(II) iodate, benzoate and formate at 30&#176;C in methanol- dimethylformamide mixtures by solubility measurements. Single-ion transfer energies were obtained by using the negligible liquid junction potential assumption, along with relevant literature data, and are in excellent agreement with values estimated from the reference electrolyte ( tatb ) assumption. The results obtained indicate that all of these salts are heteroselectively solvated in these mixtures, with Cu2+ being preferentially solvated by dmf and the anions by MeOH. This model is consistent with calculations based on the quasi-lattice quasi-chemical theory of Marcus and with solvent transport numbers obtained from e.m.f . measurements. 
