
TY  - JOUR
A1  - Varghese, AV 
A1  - Kalidas, C 
A1  - Singh, P 
A1  - Hefter, G 
T1  - Gibbs Transfer Energies and Solvent Transport Numbers of Some Copper(II) Salts in Methanol-Dimethylformamide Mixtures
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1995
VL  - 48
IS  - 5
SP  - 987
EP  - 996
KW  - 
UR  - https://doi.org/10.1071/CH9950987 
N2  - Standard Gibbs energies of transfer have been determined for copper(II) iodate, benzoate and formate at 30&#176;C in methanol- dimethylformamide mixtures by solubility measurements. Single-ion transfer energies were obtained by using the negligible liquid junction potential assumption, along with relevant literature data, and are in excellent agreement with values estimated from the reference electrolyte ( tatb ) assumption. The results obtained indicate that all of these salts are heteroselectively solvated in these mixtures, with Cu2+ being preferentially solvated by dmf and the anions by MeOH. This model is consistent with calculations based on the quasi-lattice quasi-chemical theory of Marcus and with solvent transport numbers obtained from e.m.f . measurements. 
ER  -

