
%0 Journal Article
%A Hall, VJ 
%A Tiekink, ERT 
%T Characterization and X-Ray Structure of the Adduct Formed Between Triphenyltin Chloride and Dicyclohexylphosphinyl-N-methyl(thioformamide): Ph<sub>3</sub>Sn[Cy<sub>2</sub>P(O)C(S)N(H)Me]Cl
%J Australian Journal of Chemistry
%D 1995/09/01
%V 48
%N 9
%P 1659-1664
%K 
%R https://doi.org/10.1071/CH9951659
%U https://www.publish.csiro.au/paper/CH9951659 
%X The reaction of Ph3SnCl and Cy2P(O)C(S)N(H)Me yields the air-stable adduct Ph3Sn[Cy2P(O)-C(S)N(H)Me]Cl which features a trigonal bipyramidal tin atom geometry with a chlorine atom [Sn-Cl 2.4236(9)&#506;] and an oxygen atom [Sn-O 2.523(2)&#506;], derived from a monodentate phosphinyl(thioformamide) ligand, occupying the axial positions. The pale-yellow crystals are monoclinic, space group P21/c with unit cell dimensions a 10.050(1), b 16.501(1), c 19.273(1) &#506;, &#946; 102.12(1)&#176;, Z 4; the structure was refined to final R 0.031 by using 5384 reflections. 
