
%0 Journal Article
%A Campi, EM 
%A Jackson, WR 
%A Mccubbin, QJ 
%A Trnacek, AE 
%T The Stereochemistry of Organometallic Compounds. XLIII. Rhodium-Catalysed Reactions of 2-(Alkenyloxy)benzylamines and 2-(N-Allyl-N-benzylamino)benzylamine
%J Australian Journal of Chemistry
%D 1996/02/01
%V 49
%N 2
%P 219-230
%K 
%R https://doi.org/10.1071/CH9960219
%U https://www.publish.csiro.au/paper/CH9960219 
%X Reactions of 2-( allyloxy ) benzylamines with H2/CO in the presence of rhodium catalysts give 1,3-benzoxazines, and 2-(N- allyl-N-benzylamino ) benzylamine gives a quinazoline . These reactions have been shown to involve allylic cleavage followed by regioselective carbonylation at the internal carbon atom as demonstrated by crossover experiments. Reactions of longer chain ( alkenyloxy ) benzylamines under similar conditions give polymeric material. 
