
TY  - JOUR
A1  - Campi, EM 
A1  - Jackson, WR 
A1  - Mccubbin, QJ 
A1  - Trnacek, AE 
T1  - The Stereochemistry of Organometallic Compounds. XLIII. Rhodium-Catalysed Reactions of 2-(Alkenyloxy)benzylamines and 2-(N-Allyl-N-benzylamino)benzylamine
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1996
VL  - 49
IS  - 2
SP  - 219
EP  - 230
KW  - 
UR  - https://doi.org/10.1071/CH9960219 
N2  - Reactions of 2-( allyloxy ) benzylamines with H2/CO in the presence of rhodium catalysts give 1,3-benzoxazines, and 2-(N- allyl-N-benzylamino ) benzylamine gives a quinazoline . These reactions have been shown to involve allylic cleavage followed by regioselective carbonylation at the internal carbon atom as demonstrated by crossover experiments. Reactions of longer chain ( alkenyloxy ) benzylamines under similar conditions give polymeric material. 
ER  -

