
TY  - JOUR
A1  - Adams, CJ 
A1  - Bruce, MI 
T1  - Preparation and Characterization of the Dicarbon Cluster Complex Ru<sub>5</sub>(&#956;<sub>5</sub>-C<sub>2</sub>)(&#956;<sub>5</sub>-SMe)<sub>2</sub>(&#956;-PBu<sub>2</sub>)<sub>2</sub>(CO)<sub>11</sub>
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1996
VL  - 49
IS  - 4
SP  - 517
EP  - 520
KW  - 
UR  - https://doi.org/10.1071/CH9960517 
N2  - The preparation of the bis -tertiary phosphine C2(Pbu2)2 ( dpba ) is described. Pyrolysis of the ruthenium carbonyl derivative {Ru3(CO)11}2(&#956;- dbpa ) gives Ru5(&#956;5-C2PBu2)(&#956;-PBu2)(CO)13[in 41% overall yield from Ru3(CO)12)] which in turn reacts with Me2S2 to give Ru5(&#956;5-C2)(&#956;5-SMe)2(&#956;-PBu2)2(CO)11(19%). 
ER  -

