
%0 Journal Article
%A Chai, CLL 
%A Hay, DB 
%A King, AR 
%T Selectivity in Radical Reactions of Alanylglycine Anhydride Derivatives
%J Australian Journal of Chemistry
%D 1996/05/01
%V 49
%N 5
%P 605-610
%K 
%R https://doi.org/10.1071/CH9960605
%U https://www.publish.csiro.au/paper/CH9960605 
%X Functionalization of N,N&#8242;- disubstituted  alanylglycine anhydrides under radical conditions is described. The radical (7), generated ( i ) from reactions of N,N'- disubstituted  alanylglycine anhydrides with N- bromosuccinimide , and (ii) from related bromo compounds by reaction with tributyltin  deuteride , undergoes carbon-bromine and carbon-deuterium bond formation with moderate to high diastereoselectivities depending on the N- substituents present. 
