
%0 Journal Article
%A Dunlop, E.C. 
%A Browne, M.V. 
%A Tadiar, E.F. 
%T DEPLETION OF GAS RESERVOIRS BY MOLECULAR DIFFUSION &#x2014; A CASE STUDY
%J The APPEA Journal
%D 1992/06/30
%V 32
%N 1
%P 369-390
%K 
%R https://doi.org/10.1071/AJ91029
%U https://www.publish.csiro.au/paper/AJ91029 
%X Recent drilling in the southern Cooper-Eromanga basins of eastern central Australia has provided evidence to suggest that Permian gas reservoirs have been depleted by molecular diffusion.Diffusion is the process by which matter is transported along a concentration gradient, as a result of random molecular motion. It is a common and ubiquitous phenomenon in geological environments.In the Toolachee and Nappacoongee-Murteree blocks of PELs 5 and 6, channel sandstones of the Permian Patchawarra Formation are faulted or subcrop against the Murteree Horst basement high. The Lower-Middle Jurassic Hutton Sandstone was deposited directly over the exposed surface of this feature and the surrounding eroded Permo-Triassic topography. As a result, the truncated Patchawarra Formation sandstone reservoirs are in contact with the overlying Hutton Sandstone, a major fresh water aquifer within the Great Artesian Basin. There is an anomalous increase in Patchawarra Formation water resisitivity around the Murteree Horst, suggesting that fluid communication with the Hutton Sandstone has allowed ionic diffusion to reduce the salinity of the Patchawarra reservoirs.Fluid communication has existed between the Patchawarra and Hutton reservoir systems for the duration of hydrocarbon generation and migration. It is proposed that the diffusion of solution gas towards the Murteree Horst has lowered basinward Patchawarra gas concentrations below saturation point, to the extent that gas generated in nearby source areas has gone into solution rather than migrating in the gaseous phase to form accumulations. Hydrocarbon traps immediately basinward of the Patchawarra edge should contain gas only if the rate of supply from source rocks has been greater than the rate of loss by diffusion. Gas accumulations may be shielded from depletion by source areas or other accumulations which are closer to the Patchawarra edge.The diffusion model has a negative impact on the prospectivity of Permian gas targets in marginal source areas of the Cooper Basin where reservoir communication exists between potential gas reservoirs and the Great Artesian Basin aquifers. Nevertheless, the recognition of this process may be used to advantage in identifying areas where further gas exploration should be curtailed. Such action may improve the drilling success rate in the region. 
