The Interaction Energy of an Isolated Monovalent Ion

Abstract

The interaction energy of a monovalent ion in an aqueous medium at 25°C is determined. It is also found that the water molecules in the first hydration shell of the ion have a mean dipole moment far in excess of their permanent dipole moments. Thus, for example, the increase in the dipole moment of the attached water molecules. due to the presence of an ion is about 60% for the small four-coordinated Li+ ion and about 30% for the larger four-coordinated 1- ion. Calculations are also carried out on the assumption that the ions are six coordinated.