Register      Login
The APPEA Journal The APPEA Journal Society
Journal of Australian Energy Producers
RESEARCH ARTICLE (Non peer reviewed)

Measurement of gas contents in shale reservoirs – impact of gas density and implications for gas resource estimates

Jamiu M. Ekundayo A B C , Reza Rezaee A and Chunyan Fan A
+ Author Affiliations
- Author Affiliations

A Western Australian School of Mines: Minerals, Energy and Chemical Engineering, Curtin University, Perth, WA 6102, Australia.

B State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, Sichuan 610500, China.

C Corresponding author. Email: jamiu.ekundayo@postgrad.curtin.edu.au

The APPEA Journal 61(2) 606-610 https://doi.org/10.1071/AJ20177
Accepted: 15 March 2021   Published: 2 July 2021

Abstract

Gas shale reservoirs pose unique measurement challenges due to their ultra-low petrophysical properties and complicated pore structures. A small variation in an experimental parameter, under high-pressure conditions, may result in huge discrepancies in gas contents and the resource estimates derived from such data. This study illustrates the impact of the equation of state on the gas content determined for a shale sample. The gas content was determined from laboratory-measured high-pressure methane adsorption isotherms and theoretically described by a hybrid type model. The modelling involved the use of the Dubinin–Radushkevich isotherm to obtain the adsorbed phase density followed by the Langmuir isotherm to describe the resultant absolute adsorptions. Significant variations were observed in measured adsorption isotherms due to the variations in gas densities calculated from different equations of states. The model parameters and the gas in-place volumes estimated from those parameters also varied significantly.

Keywords: high-pressure volumetric analysis, adsorption isotherms, gas contents, gas shale reservoirs, Dubinin–Radushkevich (DR) isotherm, Langmuir isotherm.

Jamiu Ekundayo is a PhD student in the Discipline of Petroleum Engineering, Western Australian School of Mines (WASM): Minerals, Energy and Chemical Engineering at Curtin University. His PhD is focused on shale gas sorption hysteresis and how it affects gas production from shale gas reservoirs. He holds a MSc degree in Petroleum Engineering from the Petroleum Institute (now part of Khalifa University), Abu Dhabi, UAE and a BSc (hons) degree in Petroleum & Gas Engineering from University of Lagos, Nigeria. He has over 10 years of reservoir engineering, teaching and research, and data science experience.

Professor Reza Rezaee of Curtin University has a PhD in Reservoir Characterization. His research has been mostly on integrated solutions for reservoir characterisation, formation evaluation and petrophysics. He has also worked on the application of artificial intelligence in the oil and gas industry for many years. Currently, he is focused on unconventional gas including shale gas and tight gas sand studies. He has over 27 years of experience in academia and has published more than 170 peer-reviewed journals and conference papers and is the author of five books. As a founder of the ‘Unconventional Gas Research Group’ of Australia, he has established a unique and highly sophisticated research lab at the Department of Petroleum Engineering, Curtin University. This lab was established to research petrophysical evaluation of tight gas sands and shale gas formations. He is the Editor-in-Chief of Improved Oil and Gas Recovery journal, Associate Editor of Marine and Petroleum Geology and Associate Editor of Geofluids.

Dr Chunyan Fan received her BEng from China University of Petroleum (East China) and doctoral degree from the University of Queensland. She is currently a Senior Lecturer in Chemical Engineering, Curtin University. Her research is mainly focused on the fundamental mechanisms of various adsorption phenomena in physical science and engineering and is a member of the International Adsorption Society. She has published more than 40 articles in international well reputed journals in this discipline and is the recipient of DECRA (2016).


References

Bell, G. J., and Rakop, K. C. (1986). Hysteresis of Methane/Coal Sorption Isotherms. Paper presented at the 61st SPE-ATCE, New Orleans, LA. 10.2118/15454-MS

Curtis, J. B. (2002). Fractured shale-gas systems. AAPG Bulletin 86, 1921–1938.
Fractured shale-gas systems.Crossref | GoogleScholarGoogle Scholar |

Ekundayo, J. M., and Rezaee, R. (2019a). Effect of equation of states on high pressure volumetric measurements of methane-coal sorption isotherms – Part 1: volumes of free space and methane adsorption isotherms. Energy & Fuels 33, 1029–1036.
Effect of equation of states on high pressure volumetric measurements of methane-coal sorption isotherms – Part 1: volumes of free space and methane adsorption isotherms.Crossref | GoogleScholarGoogle Scholar |

Ekundayo, J. M., and Rezaee, R. (2019b). Volumetric measurements of methane-coal adsorption and desorption isotherms – effects of equations of state and implication for initial gas reserves. Energies 12, 2022.
Volumetric measurements of methane-coal adsorption and desorption isotherms – effects of equations of state and implication for initial gas reserves.Crossref | GoogleScholarGoogle Scholar |

Ekundayo, J. M., Rezaee, R., and Fan, C. (2020). Experimental investigation and mathematical modelling of shale gas adsorption and desorption hysteresis. Journal of Natural Gas Science and Engineering 88, 103761.
Experimental investigation and mathematical modelling of shale gas adsorption and desorption hysteresis.Crossref | GoogleScholarGoogle Scholar |

Gasparik, M., Rexer, T. F. T., Aplin, A. C., Billemont, P., Weireld, G. D., Gensterblum, Y., Henry, M., Krooss, B. M., Liu, S., Ma, X., Sakurovs, R., Song, Z., Staib, G., Thomas, K. M., and Zhang, T. (2014). First international inter-laboratory comparison of high-pressure CH4, CO2 and C2H6 sorption isotherms on carbonaceous shales. International Journal of Coal Geology 132, 131–146.
First international inter-laboratory comparison of high-pressure CH4, CO2 and C2H6 sorption isotherms on carbonaceous shales.Crossref | GoogleScholarGoogle Scholar |

Goodman, A. L., Busch, A., Duffy, G. J., Fitzgerald, J. E., Gasem, K. A. M., Gensterblum, Y., Krooss, B. M., Levy, J., Ozdemir, E., Pan, Z., Robinson, R. L., Schroeder, K., Sudibandriyo, M., and White, C. M. (2004). An inter-laboratory comparison of CO2 isotherms measured on argonne premium coal samples. Energy & Fuels 18, 1175–1182.
An inter-laboratory comparison of CO2 isotherms measured on argonne premium coal samples.Crossref | GoogleScholarGoogle Scholar |

King, G. R. (1993). Material-balance techniques for coal-seam and devonian shale gas reservoirs with limited water influx. SPE Reservoir Engineering 8, 67–72.
Material-balance techniques for coal-seam and devonian shale gas reservoirs with limited water influx.Crossref | GoogleScholarGoogle Scholar |

Langmuir, I. (1918). The adsorption of gases on plane surfaces of glass, mica and platinum. Journal of the American Chemical Society 40, 1361–1403.
The adsorption of gases on plane surfaces of glass, mica and platinum.Crossref | GoogleScholarGoogle Scholar |

Lee, B. I., and Kesler, M. G. (1975). A generalized thermodynamic correlation based on three-parameter corresponding states. AIChE Journal 21, 510–527.
A generalized thermodynamic correlation based on three-parameter corresponding states.Crossref | GoogleScholarGoogle Scholar |

Lemmon, E. W., McLinden, M. O., and Huber, M. L. (2002). NIST Standard Reference Database 23: Reference Fluid Thermodynamic and Transport Properties-REFPROP (Version 7.0). (Gaithersburg: National Institute of Standards and Technology).

McCarty, R. D., and Arp, V. D. (1990). A New Wide Range Equation of State for Helium. In: ‘Advances in Cryogenic Engineering’. Advances in Cryogenic Engineering, vol 35. (Ed. R. W. Fast) pp. 1465–1475. (Springer: Boston, MA). 10.1007/978-1-4613-0639-9_174

Merey, S., and Sinayuc, C. (2016). Gas-in-place calculations in shale gas reservoirs using experimental adsorption data with adsorption models. The Canadian Journal of Chemical Engineering 94, 1683–1692.
Gas-in-place calculations in shale gas reservoirs using experimental adsorption data with adsorption models.Crossref | GoogleScholarGoogle Scholar |

Peng, D.-Y., and Robinson, D. B. (1976). A new two-constant equation of state. Industrial & Engineering Chemistry Fundamentals 15, 59–64.
A new two-constant equation of state.Crossref | GoogleScholarGoogle Scholar |

Sakurovs, R., Day, S., Weir, S., and Duffy, G. (2007). Application of a modified Dubinin−Radushkevich equation to adsorption of gases by coals under supercritical conditions. Energy & Fuels 21, 992–997.
Application of a modified Dubinin−Radushkevich equation to adsorption of gases by coals under supercritical conditions.Crossref | GoogleScholarGoogle Scholar |

Setzmann, U., and Wagner, W. (1991). A new equation of state and tables of thermodynamic properties for methane covering the range from the melting line to 625 K at pressures up to 100 MPa. Journal of Physical and Chemical Reference Data 20, 1061–1155.
A new equation of state and tables of thermodynamic properties for methane covering the range from the melting line to 625 K at pressures up to 100 MPa.Crossref | GoogleScholarGoogle Scholar |

Soave, G. S. (1999). An effective modification of the Benedict-Webb-Rubin equation of state. Fluid Phase Equilibria 164, 157–172.
An effective modification of the Benedict-Webb-Rubin equation of state.Crossref | GoogleScholarGoogle Scholar |