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RESEARCH ARTICLE

Mineralogy and geochemical properties of some upland soils from different sedimentary formations in south-eastern Nigeria

C. A. Igwe A C , M. Zarei B and K. Stahr B
+ Author Affiliations
- Author Affiliations

A Department of Soil Science, University of Nigeria, Nsukka, Nigeria.

B Institut für Bodenkunde und Standortslehre (310), Universität Hohenheim, D-70593 Stuttgart, Germany.

C Corresponding author. Email: charigwe1@hotmail.com

Australian Journal of Soil Research 47(4) 423-432 https://doi.org/10.1071/SR08204
Submitted: 16 September 2008  Accepted: 26 March 2009   Published: 30 June 2009

Abstract

Geochemical and mineralogical properties of soil can be used to assess their agricultural productivity potential. Ten soils from 4 geological formations in the south-eastern Nigeria were studied. Soil samples were taken from typical A and B horizons from each soil. The soil properties assessed were the free forms of Fe and Al, particle size distribution, total elements, and clay mineralogy. The soils are deep and highly weathered. Crystalline Fe and Al were more dominant than amorphous or less crystalline forms. The geochemical properties of the soils are dominated by SiO2, Al2O3, and Fe2O3, whereas MgO, TiO2, and ZrO2 occur in moderate to low quantities. Other basic elements such as Na2O, K2O, and CaO are very low in the soils, with an insignificant role in their genesis. The low contents of these elements in the soil may be the cause of their low nutrient release and storage in the soil. Ferritisation, laterisation, and kaolinitisation are the major pedogenic processes in the soil. The dominant clay mineral in all the soils was kaolinite; other minerals present though less common were illite, vermiculite, and smectites. Based on elemental contents and clay mineralogy, the soils can be grouped into 3 distinct groups: those with only kaolinite, illite, and vermiculites; and those that also contain smectite. These groupings can indicate the agricultural fertility potential.

Additional keywords: Fe oxide, Al oxide, pedogenic processes, clay mineralogy, agricultural productivity.


Acknowledgements

The contribution of Alexander von Humboldt – Foundation, Bonn, Germany (AvH) through Resumption Fellowship and ‘The Equipment Donation Programme’ is acknowledged. This manuscript was written when one of the authors (CAI) was at the Abdus Salam International Centre for Theoretical Physics (ICTP) within the framework of Regular Associateship Programme.


References


Abe SS, Masunaga T, Yamamoto S, Honna T, Wakatsuki T (2006) Comprehensive assessment of the clay mineralogical composition of lowland soils in West Africa. Soil Science and Plant Nutrition 52, 479–488.
Crossref | GoogleScholarGoogle Scholar | CAS | open url image1

Akamigbo FOR (1984) The accuracy of field textures in a humid tropical environment. Soil Survey & Land Evaluation 4, 63–70. open url image1

Bjørlykke K (1989) ‘Sedimentology and petroleum geology.’ (Springer-Verlag: Berlin)

Blume HP, Schwertmann U (1969) Genetic evaluation of profile distribution of aluminum, iron and manganese oxides. Soil Science Society of America Proceedings 33, 438–444.
CAS |
open url image1

Borggaard OK , Elberling B (2004) ‘Pedological biogeochemistry.’ (Paritas Grafik A/S: Brøndby, Denmark)

Bouabid R, Nater EA, Bloom PR (1995) Characterization of the weathering status of feldspar minerals in sandy soils of Minnesota using SEM and EDX. Geoderma 66, 137–149.
Crossref | GoogleScholarGoogle Scholar | open url image1

Brodowski S, Amelung W, Haumaier L, Abetz C, Zech W (2005) Morphological and chemical properties of black carbon in physical soil fractions as revealed by scanning electron microscopy and energy-dispersive X-ray spectroscopy. Geoderma 128, 116–129.
Crossref | GoogleScholarGoogle Scholar | CAS | open url image1

Buri MM, Masunaga T, Wakatsuki T (2000) Sulfur and zinc levels as limiting factors to rice production in West Africa lowlands. Geoderma 94, 23–42.
Crossref | GoogleScholarGoogle Scholar | CAS | open url image1

Costantini EAC, Napoli R, Bragato G (1996) Properties and geographic relevance of fragipan and other close-packed horizons in a non-glaciated Mediterranean region. Geografia Fisica e Dinamica Quaternaria 19, 29–45. open url image1

Gee GW , Bauder JW (1986) Particle-size analysis. In ‘Methods of soil analysis, Part 1’. (Ed. A Klute) pp. 91–100. (American Society of Agronomy: Madison, WI)

Guillet B , Souchier B (1979) Amorphous and crystalline oxyhydroxides and oxides in soils (iron, aluminum, manganese, silicon). In ‘Constituents and properties of soils’. (Eds M Bonnear, B Souchier) pp. 21–42. (Academic Press, Inc.: London)

Igwe CA, Akamigbo FOR, Mbagwu JSC (1995) Physical properties of soils of southeastern Nigeria and the role of some aggregating agents in their stability. Soil Science 160, 431–441.
Crossref | GoogleScholarGoogle Scholar | CAS | open url image1

Igwe CA, Akamigbo FOR, Mbagwu JSC (1999) Chemical and mineralogical properties of soils in southeastern Nigeria in relation to aggregate stability. Geoderma 92, 111–123.
Crossref | GoogleScholarGoogle Scholar | CAS | open url image1

Igwe CA, Zarei M, Stahr K (2005) Mineral and elemental distribution in soils formed on the river Niger floodplain, Eastern Nigeria. Australian Journal of Soil Research 43, 147–158.
Crossref | GoogleScholarGoogle Scholar | CAS | open url image1

Jungerius PD (1964) The soils of eastern Nigeria. Publication Service Geologique de Luxemburge 14, 185–196. open url image1

Jungerius PD, Levelt TWM (1964) Clay mineralogy of soils over sedimentary rocks in eastern Nigeria. Soil Science 97, 89–95.
Crossref | GoogleScholarGoogle Scholar | open url image1

McKeague JA, Day JH (1966) Dithionite and oxalate Fe and Al as aids in differentiating various classes of soils. Canadian Journal of Soil Science 46, 13–22.
CAS |
open url image1

Mehra OP, Jackson ML (1960) Iron oxide removal from soils and clays by a dithionite-citrate system buffered with sodium bicarbonate. Clay Minerals 7, 317–327. open url image1

Nelson DW , Sommers LE (1982) Total carbon, organic carbon and organic matter. In ‘Methods of soil analysis, Part 2’. (Eds AL Page, RH Miller, DR Keeney) pp. 539–579. (American Society of Agronomy: Madison, WI)

Norra S, Lanka-Panditha M, Kramar U, Stüben D (2006) Mineralogical and geochemical patterns of urban surface soils, the example of Pforzheim, Germany. Applied Geochemistry 21, 2064–2081.
Crossref | GoogleScholarGoogle Scholar | CAS | open url image1

Ofoegbu CO (1985) A review of the geology of the Benue Trough, Nigeria. Journal of African Earth Sciences 3, 283–291.
Crossref | GoogleScholarGoogle Scholar | open url image1

Orajaka SO (1975) Geology. In ‘Nigeria in maps. Eastern states’. (Ed. GEK Ofomata) pp. 5–7. (Ethiopes Publishers: Benin City, Nigeria)

Owliaie HR, Abtahi A, Heck RJ (2006) Pedogenesis and clay mineralogical investigation of soils formed on gypsiferous and calcareous materials, on a transect, southwestern Iran. Geoderma 134, 62–81.
Crossref | GoogleScholarGoogle Scholar | CAS | open url image1

Schellmann W (1981) Considerations on the definition and classification of laterites. In ‘Laterisation processes. Proceedings of the International Seminar on Laterisation Processes’. 11–14 December 1979, Trivandrum, India. pp. 1–10.

Schwertmann U, Kämpf N (1983) Oxidos de ferro jovens em ambientes pedogeneticos brasileiros. Revieu. Brasilia Ciencia Solo 7, 251–255.
CAS |
open url image1

Soil Survey Staff (1999) ‘Soil Taxonomy.’ United States Department of Agriculture Handbook 436. 2nd edn (United States Department of Agriculture: Washington, DC)

Stahr K, Kühn J, Trommler J, Papenfuß KH, Zarei M, Singer A (2000) Palygorskite-cemented crusts (palycretes) in southern Portugal. Australian Journal of Soil Research 38, 169–188.
Crossref | GoogleScholarGoogle Scholar | open url image1

Szilas C, Møberg JP, Borggaard OK, Semoka JMR (2005) Mineralogy of characteristic well-drained soils of sub-humid to humid Tanzania. Acta Agriculture Scandinavica B – Soil and Plant Science 55, 241–251.
Crossref | GoogleScholarGoogle Scholar | CAS | open url image1

Tan HK (1982) ‘Principles of soil chemistry.’ (Marcel Dekker, Inc.: New York)

Thomas GW (1982) Exchangeable cations. In ‘Methods of soil analysis, Part 2’. (Ed. AL Page) pp. 159–165. (American Society of Agronomy: Madison, WI)

Torrent J, Schwertmann U, Schulze DG (1980) Iron oxide mineralogy of two river terraces in Spain. Geoderma 23, 191–208.
Crossref | GoogleScholarGoogle Scholar | CAS | open url image1

Wagner S, Costantini EAC, Sauer D, Stahr K (2007) Soil genesis in a marine terrace sequence of Sicily, Italy. Revista de Ciencias Geologicas 24, 247–260. open url image1

Wang WM (1997) Comparative study of the geochemistry and weathering chemistry of the modern soils and the late Miocene paleosols in the Penghu Islands (Pescadores), Taiwan. PhD Thesis, Graduate Institute of Agricultural Chemistry, National Taiwan University, Taipei, Taiwan.

Wang M, Wang W, Chiang P, Chen YM, Chang CM (2007) Clay mineralogy and major element chemistry of the early quaternary and late Miocene paleosols on Penghu Islands (Pescadores), Taiwan. Soil Science 172, 486–498.
Crossref | GoogleScholarGoogle Scholar | CAS | open url image1

Wilson MJ (1999) The origin and formation of clay minerals in soils: past, present and future perspectives. Clay Minerals 34, 7–25.
Crossref | GoogleScholarGoogle Scholar | CAS | open url image1

Zhang G, Pan J, Huang C, Gong Z (2007) Geochemical features of a soil chronosequence developed on basalt in Hainan Island, China. Revista de Ciencias Geologicas 24, 261–269. open url image1